Valence tautomerism in a cobalt-verdazyl coordination compound

Connor Fleming, Dorothy Chung, Servando Ponce, David J.R. Brook, Jeffrey Daros, Raja Das, Andrew Ozarowski, Sebastian A. Stoian

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

Coordination of 1-isopropyl-3,5-dipyridyl-6-oxoverdazyl to cobalt results in a dication best described in the solid state as a high spin cobalt(ii) ion coordinated to two radical ligands with an S = 3/2 ground state. On dissolution in acetonitrile, the cobalt(ii) form equilibrates with a cobalt(iii) valence tautomer with an S = 1/2 ground state.

Original languageEnglish
Pages (from-to)4400-4403
Number of pages4
JournalChemical Communications
Volume56
Issue number32
DOIs
Publication statusPublished - 25 Apr 2020
Externally publishedYes

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